Nanostructured Materials for Efficient Catalysis in Chemical Reactions

Park Jihoon (1), Ri Hwa Sin (2), Erdenetsetseg Chuluunbaatar (3)
(1) KAIST (Korea Advanced Institute of Science and Technology), Korea, Democratic People's Republic of,
(2) University of National Economy, Korea, Democratic People's Republic of,
(3) Ulaanbaatar University, Mongolia

Abstract

The quest for more efficient catalytic materials has intensified due to the growing demand for sustainable chemical processes. Nanostructured materials have emerged as promising candidates, offering enhanced surface area and reactivity, which can significantly improve catalytic performance. This study aims to investigate the role of nanostructured materials in catalysis, focusing on their synthesis, characterization, and application in various chemical reactions. The goal is to identify the optimal conditions for maximizing catalytic efficiency. A series of nanostructured catalysts were synthesized using sol-gel and hydrothermal methods. Characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD), were employed to analyze the structural and morphological properties of the materials. Catalytic performance was evaluated through various model reactions, such as hydrogenation and oxidation. The findings revealed that nanostructured materials exhibited significantly higher catalytic activity compared to their bulk counterparts. Specific catalysts demonstrated up to a 70% increase in reaction rates, attributed to their enhanced surface area and active sites. The study also identified optimal synthesis parameters that further improved catalytic performance. This research highlights the potential of nanostructured materials to revolutionize catalysis in chemical reactions. By optimizing synthesis methods and understanding the relationship between structure and activity, it is possible to develop more efficient catalysts for sustainable chemical processes.

Full text article

Generated from XML file

References

Abdel-Karim, R., Reda, Y., & Abdel-Fattah, A. (2020). Review—Nanostructured Materials-Based Nanosensors. Journal of The Electrochemical Society, 167(3), 037554. https://doi.org/10.1149/1945-7111/ab67aa

Barhoum, A., Jeevanandam, J., Rastogi, A., Samyn, P., Boluk, Y., Dufresne, A., Danquah, M. K., & Bechelany, M. (2020). Plant celluloses, hemicelluloses, lignins, and volatile oils for the synthesis of nanoparticles and nanostructured materials. Nanoscale, 12(45), 22845–22890. https://doi.org/10.1039/D0NR04795C

Burakova, E., Dyachkova, T., Tkachev, A., Tugolukov, E., Memetov, N., Galunin, E., & Gutnik, I. (2020). Features of obtaining an effective catalyst for synthesis of carbon nanostructured materials. Fullerenes, Nanotubes and Carbon Nanostructures, 28(4), 348–352. https://doi.org/10.1080/1536383X.2019.1711062

Chen, X., Liu, Q., Bai, T., Wang, W., He, F., & Ye, M. (2021). Nickel and cobalt sulfide-based nanostructured materials for electrochemical energy storage devices. Chemical Engineering Journal, 409, 127237. https://doi.org/10.1016/j.cej.2020.127237

Dolabella, S., Borzì, A., Dommann, A., & Neels, A. (2022). Lattice Strain and Defects Analysis in Nanostructured Semiconductor Materials and Devices by High?Resolution X?Ray Diffraction: Theoretical and Practical Aspects. Small Methods, 6(2), 2100932. https://doi.org/10.1002/smtd.202100932

Du, X., Oturan, M. A., Zhou, M., Belkessa, N., Su, P., Cai, J., Trellu, C., & Mousset, E. (2021). Nanostructured electrodes for electrocatalytic advanced oxidation processes: From materials preparation to mechanisms understanding and wastewater treatment applications. Applied Catalysis B: Environmental, 296, 120332. https://doi.org/10.1016/j.apcatb.2021.120332

Franco, F., Rettenmaier, C., Jeon, H. S., & Roldan Cuenya, B. (2020). Transition metal-based catalysts for the electrochemical CO2 reduction: From atoms and molecules to nanostructured materials. Chemical Society Reviews, 49(19), 6884–6946. https://doi.org/10.1039/D0CS00835D

Gao, Y., & Zhao, L. (2022). Review on recent advances in nanostructured transition-metal-sulfide-based electrode materials for cathode materials of asymmetric supercapacitors. Chemical Engineering Journal, 430, 132745. https://doi.org/10.1016/j.cej.2021.132745

Gonzalez-Ortiz, D., Salameh, C., Bechelany, M., & Miele, P. (2020). Nanostructured boron nitride–based materials: Synthesis and applications. Materials Today Advances, 8, 100107. https://doi.org/10.1016/j.mtadv.2020.100107

Gupta, A., Sardana, S., Dalal, J., Lather, S., Maan, A. S., Tripathi, R., Punia, R., Singh, K., & Ohlan, A. (2020). Nanostructured Polyaniline/Graphene/Fe2 O3 Composites Hydrogel as a High-Performance Flexible Supercapacitor Electrode Material. ACS Applied Energy Materials, 3(7), 6434–6446. https://doi.org/10.1021/acsaem.0c00684

Hafidh, A., Touati, F., & Sediri, F. (2020). Synthesis, charaterization and optical properties of nanostructured silica hybrid materials obtained by soft chemistry from perhydropolysilazane/1,2,4-triazole precursors. Journal of Molecular Structure, 1218, 128496. https://doi.org/10.1016/j.molstruc.2020.128496

Han, N., Ding, P., He, L., Li, Y., & Li, Y. (2020). Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO2 Reduction to Formate. Advanced Energy Materials, 10(11), 1902338. https://doi.org/10.1002/aenm.201902338

Harish, V., Tewari, D., Gaur, M., Yadav, A. B., Swaroop, S., Bechelany, M., & Barhoum, A. (2022). Review on Nanoparticles and Nanostructured Materials: Bioimaging, Biosensing, Drug Delivery, Tissue Engineering, Antimicrobial, and Agro-Food Applications. Nanomaterials, 12(3), 457. https://doi.org/10.3390/nano12030457

Ikram, M., Rashid, M., Haider, A., Naz, S., Haider, J., Raza, A., Ansar, M. T., Uddin, M. K., Ali, N. M., Ahmed, S. S., Imran, M., Dilpazir, S., Khan, Q., & Maqbool, M. (2021). A review of photocatalytic characterization, and environmental cleaning, of metal oxide nanostructured materials. Sustainable Materials and Technologies, 30, e00343. https://doi.org/10.1016/j.susmat.2021.e00343

Kumar, R., Joanni, E., Sahoo, S., Shim, J.-J., Tan, W. K., Matsuda, A., & Singh, R. K. (2022). An overview of recent progress in nanostructured carbon-based supercapacitor electrodes: From zero to bi-dimensional materials. Carbon, 193, 298–338. https://doi.org/10.1016/j.carbon.2022.03.023

Li, Y., Sun, Y., Qin, Y., Zhang, W., Wang, L., Luo, M., Yang, H., & Guo, S. (2020). Recent Advances on Water?Splitting Electrocatalysis Mediated by Noble?Metal?Based Nanostructured Materials. Advanced Energy Materials, 10(11), 1903120. https://doi.org/10.1002/aenm.201903120

Li, Z., Fan, Q., & Yin, Y. (2022). Colloidal Self-Assembly Approaches to Smart Nanostructured Materials. Chemical Reviews, 122(5), 4976–5067. https://doi.org/10.1021/acs.chemrev.1c00482

Li, Z., Zhang, X., Cheng, H., Liu, J., Shao, M., Wei, M., Evans, D. G., Zhang, H., & Duan, X. (2020). Confined Synthesis of 2D Nanostructured Materials toward Electrocatalysis. Advanced Energy Materials, 10(11), 1900486. https://doi.org/10.1002/aenm.201900486

Mahdavi, K., Zinatloo-Ajabshir, S., Yousif, Q. A., & Salavati-Niasari, M. (2022). Enhanced photocatalytic degradation of toxic contaminants using Dy2O3-SiO2 ceramic nanostructured materials fabricated by a new, simple and rapid sonochemical approach. Ultrasonics Sonochemistry, 82, 105892. https://doi.org/10.1016/j.ultsonch.2021.105892

Munawar, J., Rashid, E. U., Nawaz, S., Ali, N., Kumar, V., Iqbal, H. M. N., & Bilal, M. (2022). Nanostructured materials for water/wastewater remediation. In Integrated Environmental Technologies for Wastewater Treatment and Sustainable Development (pp. 413–432). Elsevier. https://doi.org/10.1016/B978-0-323-91180-1.00018-1

Naresh, Varnakavi., & Lee, N. (2021). A Review on Biosensors and Recent Development of Nanostructured Materials-Enabled Biosensors. Sensors, 21(4), 1109. https://doi.org/10.3390/s21041109

Niu, Y.-Q., Liu, J.-H., Aymonier, C., Fermani, S., Kralj, D., Falini, G., & Zhou, C.-H. (2022). Calcium carbonate: Controlled synthesis, surface functionalization, and nanostructured materials. Chemical Society Reviews, 51(18), 7883–7943. https://doi.org/10.1039/D1CS00519G

Prasad, C., Tang, H., Liu, Q., Bahadur, I., Karlapudi, S., & Jiang, Y. (2020). A latest overview on photocatalytic application of g-C3N4 based nanostructured materials for hydrogen production. International Journal of Hydrogen Energy, 45(1), 337–379. https://doi.org/10.1016/j.ijhydene.2019.07.070

Raha, S., & Ahmaruzzaman, Md. (2022). ZnO nanostructured materials and their potential applications: Progress, challenges and perspectives. Nanoscale Advances, 4(8), 1868–1925. https://doi.org/10.1039/D1NA00880C

Reddy, R. C. K., Lin, J., Chen, Y., Zeng, C., Lin, X., Cai, Y., & Su, C.-Y. (2020). Progress of nanostructured metal oxides derived from metal–organic frameworks as anode materials for lithium–ion batteries. Coordination Chemistry Reviews, 420, 213434. https://doi.org/10.1016/j.ccr.2020.213434

Sadhasivam, T., & Jung, H.-Y. (2020). Nanostructured bifunctional electrocatalyst support materials for unitized regenerative fuel cells. In Nanostructured, Functional, and Flexible Materials for Energy Conversion and Storage Systems (pp. 69–103). Elsevier. https://doi.org/10.1016/B978-0-12-819552-9.00003-8

Selvaraj, M., Hai, A., Banat, F., & Haija, M. A. (2020). Application and prospects of carbon nanostructured materials in water treatment: A review. Journal of Water Process Engineering, 33, 100996. https://doi.org/10.1016/j.jwpe.2019.100996

Sengupta, S., Shankaranarayana Anantha, M., Basavarajaiah Muralidhara, H., & Kundu, M. (2022). Nanostructured MnO2/CeO2 composite as anode material for high performance Li-ion battery. Materials Letters, 308, 131298. https://doi.org/10.1016/j.matlet.2021.131298

Sharma, R., Kumar, A., Devgan, M., Kaur, A., Kaur, H., Choudhary, A., Kumar Dixit, A., Singh, K., & Mehta, S. (2022). Applications of nanostructured materials in agriculture: A review. Materials Today: Proceedings, 69, 549–555. https://doi.org/10.1016/j.matpr.2022.09.314

Shi, H., Gao, S., Liu, X., Wang, Y., Zhou, S., Liu, Q., Zhang, L., & Hu, G. (2024). Recent Advances in Catalyst Design and Performance Optimization of Nanostructured Cathode Materials in Zinc–Air Batteries. Small, 20(25), 2309557. https://doi.org/10.1002/smll.202309557

Tang, X., Liu, D., Wang, Y.-J., Cui, L., Ignaszak, A., Yu, Y., & Zhang, J. (2021). Research advances in biomass-derived nanostructured carbons and their composite materials for electrochemical energy technologies. Progress in Materials Science, 118, 100770. https://doi.org/10.1016/j.pmatsci.2020.100770

Tian, X., Cui, X., Lai, T., Ren, J., Yang, Z., Xiao, M., Wang, B., Xiao, X., & Wang, Y. (2021). Gas sensors based on TiO2 nanostructured materials for the detection of hazardous gases: A review. Nano Materials Science, 3(4), 390–403. https://doi.org/10.1016/j.nanoms.2021.05.011

Wang, K., Xing, G., Song, Q., & Xiao, S. (2021). Micro? and Nanostructured Lead Halide Perovskites: From Materials to Integrations and Devices. Advanced Materials, 33(6), 2000306. https://doi.org/10.1002/adma.202000306

Wibowo, A., Marsudi, M. A., Amal, M. I., Ananda, M. B., Stephanie, R., Ardy, H., & Diguna, L. J. (2020). ZnO nanostructured materials for emerging solar cell applications. RSC Advances, 10(70), 42838–42859. https://doi.org/10.1039/D0RA07689A

Xu, X., Zhang, S., Tang, J., Pan, L., Eguchi, M., Na, J., & Yamauchi, Y. (2020). Nitrogen-doped nanostructured carbons: A new material horizon for water desalination by capacitive deionization. EnergyChem, 2(5), 100043. https://doi.org/10.1016/j.enchem.2020.100043

Yan, J., Li, S., Lan, B., Wu, Y., & Lee, P. S. (2020). Rational Design of Nanostructured Electrode Materials toward Multifunctional Supercapacitors. Advanced Functional Materials, 30(2), 1902564. https://doi.org/10.1002/adfm.201902564

Zhang, W., Li, H., Hopmann, E., & Elezzabi, A. Y. (2020). Nanostructured inorganic electrochromic materials for light applications. Nanophotonics, 10(2), 825–850. https://doi.org/10.1515/nanoph-2020-0474

Zheng, B., Fan, J., Chen, B., Qin, X., Wang, J., Wang, F., Deng, R., & Liu, X. (2022). Rare-Earth Doping in Nanostructured Inorganic Materials. Chemical Reviews, 122(6), 5519–5603. https://doi.org/10.1021/acs.chemrev.1c00644

Zhou, T., & Zhang, T. (2021). Recent Progress of Nanostructured Sensing Materials from 0D to 3D: Overview of Structure–Property?Application Relationship for Gas Sensors. Small Methods, 5(9), 2100515. https://doi.org/10.1002/smtd.202100515

Authors

Park Jihoon
parkjihonn@gmail.com (Primary Contact)
Ri Hwa Sin
Erdenetsetseg Chuluunbaatar
Jihoon, P., Sin, R. H., & Chuluunbaatar, E. (2025). Nanostructured Materials for Efficient Catalysis in Chemical Reactions. Research of Scientia Naturalis, 2(3), 112–123. https://doi.org/10.70177/scientia.v2i3.2013

Article Details